Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids   总被引：16，自引：2，他引：16  

Shifeng Dai  Chen-Lin Chou  Mei Yue  Kunli Luo  Deyi Ren   《International Journal of Coal Geology》2005,61(3-4):241-258

This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, R_r=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids.  相似文献   

9: Processes of tectonism, magmatism and mineralization: Lessons from Europe     

Derek Blundell  Nicholas Arndt  Peter R. Cobbold  Christoph Heinrich 《Ore Geology Reviews》2005,27(1-4):333

Metallogenic provinces in Europe range in age from the Archaean to the Neogene. Deposit types include porphyry copper and epithermal Cu–Au, volcanic-hosted massive sulphide (VMS), orogenic gold, Fe-oxide–Cu–Au, anorthosite Fe–Ti-oxide and sediment-hosted base-metal deposits. Most of them formed during short-lived magmatic events in a wide range of tectonic settings; many can be related to specific tectonic processes such as subduction, hinge retreat, accretion of island arcs, continental collision, lithosphere delamination or slab tear. In contrast, most sediment-hosted deposits in Europe evolved in extensional, continental settings over significant periods of time. In Europe, as elsewhere, ore formation is an integral part of the geodynamic evolution of the Earth's crust and mantle. Many tectonic settings create conditions conducive to the generation of water-rich magma, but the generation of ore deposits appears to be restricted to locations and short periods of change in temperature and stress, imposed by transitory plate motions. Crustal influence is evident in the strong structural controls on the location and morphology of many ore deposits in Europe. Crustal-scale fault–fracture systems, many involving strike-slip elements, have provided the fabric for major plumbing systems. Rapid uplift, as in metamorphic core complexes, and hydraulic fracturing can generate or focus magmatic–hydrothermal fluid flow that may be active for time spans significantly less than a million years. Once a hydrologically stable flow is established, ore formation is strongly dependent on the steep temperature and pressure gradients experienced by the fluid, particularly within the upper crust. In Europe, significant fracture porosity deep in the crystalline basement (1%) is not only important for magmatic–hydrothermal systems, but allows brines to circulate down through sedimentary basins and then episodically upward, expelled seismically to produce sediment-hosted base-metal deposits and Kupferschiefer copper deposits. Emerging research, stimulated by GEODE, can improve the predicting power of numerical simulations of ore-forming processes and help discover the presence of orebodies beneath barren overburden.  相似文献   

Lead-arsenic soil geochemical study as an exploration guide over the Killik volcanogenic massive sulfide deposit, Northeastern Turkey   总被引：3，自引：0，他引：3  

E. ifti  H. Kolayli  S.Tokel 《Journal of Geochemical Exploration》2005,86(1):49-59

A mountainous terrain, the eastern Pontide tectonic belt, located in northeastern Turkey, contains more than 60 known volcanogenic massive sulfide (VMS) deposits that differ in reserves (0.1–30 million tonnes) and grades. Soil geochemistry is conventionally used in exploration programs to discover concealed VMS deposits in the region. In the present study, Pb and As element pair were used as pathfinder elements to investigate the relationship of their anomalies to a completely delineated ore deposit (Killik VMS deposit) in an orientation survey that served as a natural physical model. Two hundred forty soil samples were analyzed in the present study. The two elements, which represent the opposite ends of the mobility range, revealed high contrast and overlapped each other at the location of the ore deposit due to enhancement of the anomalies by hydromorphic dispersion, which is an indication that soil samples would produce reliable results. The successful delineation of the deposit is remarkable considering the rough topography and the climatic limitations. Previously the extremely moist and temperate climate was thought to cause excessive leaching of the trace element pathfinders from the ore deposits to produce extensive anomalies usually extending away from the mineralization thus, leading to erroneous results and/or extensive anomalous areas. But the present research has shown that the method can be used effectively if the sampling and data evaluation is carefully conducted.  相似文献   

Under stress permeability determination of the Meuse/Haute-Marne mudstone     

S. Escoffier  F. Homand  N. Hoteit 《Engineering Geology》2005,81(3):329-340

In the underground waste isolation projects such as the ANDRA'one in the site of Bure, the transport properties of the surrounding rock mass is of fundamental importance. To measure very low permeability, we use the modified version of the pulse test proposed by Hsieh et al. [Hsieh, P.A., Tracy, J.V., Neuzil, C.E., Bredehoeft, J.D., Silliman, S.E., 1981. A transient laboratory method for determining the hydraulic properties of ‘tight’ rocks — I. Theory. Int. J. Rock Mech. Min. Sci. Geomech. Abstr. Vol. 18, pp. 245-252] which enables the intrinsic permeability, k, and the specific storage coefficient, S_s, of rocks such as mudstone to be characterized. In this paper, the special effort performed on the laboratory apparatus design, to ensure a good sensitivity of the rock response with respect to both parameters, k and S_s, is presented. In addition, two parameters identification procedures are proposed: the graphical method given by Hsieh et al. [Hsieh, P.A., Tracy, J.V., Neuzil, C.E., Bredehoeft, J.D., Silliman, S.E., 1981. A transient laboratory method for determining the hydraulic properties of ‘tight’ rocks — I. Theory. Int. J. Rock Mech. Min. Sci. Geomech. Abstr. Vol. 18, pp. 245-252] and a parameter identification based on the solution of an inverse problem. The efficiency of the apparatus design and the parameters identification procedures is then demonstrated though some pulse tests performed on the Meuse/Haute-Marne mudstone.  相似文献   

近20年京津唐主体城区地表热场空间特征变化分析   总被引：3，自引：1，他引：2  

于琛  胡德勇  张旸  曹诗颂  段欣  张亚妮 《地理科学》2019,39(6):1016-1024

基于Landsat遥感影像获取京津唐主体城区1995~2015年地表温度(Land Surface Temperature, LST)和不透水地表盖度(Impervious Surface Percentage, ISP)数据。采用热点聚集和阈值分割法,依据地表的温度和不透水盖度属性将京津唐主体城区划分成9种地表热场类型,分析并探讨地表热场的发展规律、年际变化状况和区域贡献作用。研究发现,京津唐主体城区地表温度与不透水地表盖度间存在显著的正向相关关系,两者分别呈现“阶梯降”和“两端高、中间低”的变化特征。京津唐主体城区地表热场的发展主轴保持在西北-东南方向,且随时间推移沿主轴呈聚集态势。 京津唐主体城区地表热场的影响范围在空间上持续扩张,对于不同的主体城区,其在整体区域的热场贡献中有差异化表现。  相似文献   

Three dimensional numerical simulation of residential building on shrink–swell soils in response to climatic conditions          下载免费PDF全文

Xiong Zhang  Jean‐Louis Briaud 《国际地质力学数值与分析法杂志》2015,39(13):1369-1409

Shrink–swell soils can cause distresses in buildings, and every year, the economic loss associated with this problem is huge. This paper presents a comprehensive system for simulating the soil–foundation–building system and its response to daily weather conditions. Weather data include rainfall, solar radiation, air temperature, relative humidity, and wind speed, all of which are readily available from a local weather station or the Internet. These data are used to determine simulation flux boundary conditions. Different methods are proposed to simulate different boundary conditions: bare soil, trees, and vegetation. A coupled hydro‐mechanical stress analysis is used to simulate the volume change of shrink–swell soils due to both mechanical stress and water content variations. Coupled hydro‐mechanical stress‐jointed elements are used to simulate the interaction between the soil and the slab, and general shell elements are used to simulate structural behavior. All the models are combined into one finite element program to predict the entire system's behavior. This paper first described the theory for the simulations. A site in Arlington, Texas, is then selected to demonstrate the application of the proposed system. Simulation results are shown, and a comparison between measured and predicted movements for four footings in Arlington, Texas, over a 2‐year period is presented. Finally, a three‐dimensional simulation is made for a virtual residential building on shrink–swell soils to identify the influence of various factors. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Experimental characterization of the impact of temperature and humidity on the breakdown of soil water repellency in sandy soils and composts          下载免费PDF全文

Amii Whelan  Cedric Kechavarzi  Frederic Coulon  Stefan H. Doerr 《水文研究》2015,29(8):2065-2073

Soil water repellency is a widespread phenomenon with the capacity to alter hydrological and geomorphological processes. Water repellency decays with time, and the consequences are only of concern during the timescale at which the water repellency persists. This study aimed to characterize the influence of temperature and humidity on the breakdown of water repellency. Apparent contact angle measurements were carried out on samples consisting of sand treated with stearic acid as well as naturally repellent dune sands and composts. Temperature and humidity were controlled using a cooled incubator and a purpose designed enclosed box in which humidity could be raised or lowered. Results showed the contact angle of the stearic‐acid‐treated sands decayed with time and that there was a significant increase with stearic acid concentration. For all samples, the decay in apparent contact angle could be described with a continuous breakdown model. The stearic‐acid‐treated sands showed a significant increase in contact angle with relative humidity at a temperature of 10 and 20 °C. These differences diminished with increasing temperature. Similar results were seen for the dune sands and composts. Despite the influence of temperature and humidity on contact angles, there was no significant change in the rate at which the contact angle decayed in any sample. Absolute humidity was found to provide a more relevant indicator than relative humidity when assessing the influence of humidity on repellency over a range of temperatures. The contact angle initially increased with absolute humidity before plateauing owing to the confounding effect of temperature. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Variation of stream temperature among mesoscale habitats within stream reaches: southern Appalachians          下载免费PDF全文

S. Lynsey Long  C. Rhett Jackson 《水文研究》2014,28(7):3041-3052

Stream mesoscale habitats have systematic topographic relationships to hyporheic flow patterns, which may create predictable temperature variation between mesoscale habitat types. We investigated whether systematic differences in temperature metrics occurred between mesoscale habitats within reaches of small streams tributary to the upper Little Tennessee River, southern Appalachians. Surface water temperature was recorded over three or four mid‐summer days in four mesoscale habitat types: riffle, main riffle, pool and alcove in 44 stream segments (sites). Temperature metrics were calculated for each mesoscale habitat relative to the mean value of the metric over the stream: Δ maximum temperature, Δ average maximum temperature and Δ maximum daily variation and also for each site: standard deviation of the maximum temperature and average diurnal variation (ADV). Sites were categorized as fully or partially forested. Pool tailouts had statistically significantly lower Δ maximum temperature and Δ average maximum temperature than riffle tailouts in partially forested sites, although differences were small. This was the opposite of what was expected in the presence of hyporheic exchange, indicating hyporheic exchange is not a dominant driver of mesoscale habitat temperatures at these sites. Temperature differences between mesoscale habitat units were small and unlikely to have ecological significance. We also evaluated relationships between stream temperature and riparian condition, watershed % impervious surfaces, watershed % non‐forested and elevation. ADV and standard deviation of the maximum temperature were significantly higher in partially forested sites, indicating that partially forested sites have greater temperature ranges and spatial variation of maximum temperatures. ADV decreased with elevation and increased with % impervious surfaces. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Estimation of daily stream water temperatures with a Bayesian regression approach          下载免费PDF全文

Mohammad M. Sohrabi  Rohan Benjankar  Daniele Tonina  Seth J. Wenger  Daniel J. Isaak 《水文研究》2017,31(9):1719-1733

Stream water temperature plays a significant role in aquatic ecosystems where it controls many important biological and physical processes. Reliable estimates of water temperature at the daily time step are critical in managing water resources. We developed a parsimonious piecewise Bayesian model for estimating daily stream water temperatures that account for temporal autocorrelation and both linear and nonlinear relationships with air temperature and discharge. The model was tested at 8 climatically different basins of the USA and at 34 sites within the mountainous Boise River Basin (Idaho, USA). The results show that the proposed model is robust with an average root mean square error of 1.25 °C and Nash–Sutcliffe coefficient of 0.92 over a 2‐year period. Our approach can be used to predict historic daily stream water temperatures in any location using observed daily stream temperature and regional air temperature data.  相似文献   

北半球热带中太平洋与印度洋海表温度梯度对夏季西北太平洋热带气旋生成频数变化的影响     

方珂  余锦华 《热带海洋学报》2019,38(5):42-51

基于1951—2018年哈德里中心海温资料、美国气象环境预报中心和美国国家大气研究中心再分析资料和第四代欧洲中心汉堡模式, 针对1994年、2018年等西北太平洋热带气旋(TC)生成异常多的年份, 研究了引起TC增加的海表温度异常(SSTA)模态及其影响机制。结果表明, 北半球热带中太平洋增暖与印度洋变冷是夏季西北太平洋TC生成频数增加的主要原因, 北大西洋负三极型式SSTA促使TC生成的进一步增加。热带中太平洋增暖与印度洋冷却在菲律宾以东激发出西风异常和气旋性环流异常。北大西洋负三极型式SSTA在我国南海、菲律宾至东南沿岸激发出气旋性环流异常。前者在西北太平洋中部, 后者在南海产生有利于TC生成的局地环境。1994年和2018年夏季热带中太平洋出现暖SSTA、印度洋为冷SSTA、北大西洋呈现负三极型式SSTA, 西北太平洋TC生成频数极端增多。近30年来, 当出现热带中太平洋增暖和印度洋冷却时, 北大西洋表现出比1989年以前更强的负三极型式SSTA, 使西北太平洋TC生成频数和北半球热带印度洋-太平洋SSTA梯度的线性相关更显著。  相似文献